|
|
(3S)-hydroxyhexadecanoyl-CoA <=> trans-2-hexadecenoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
4.2.1.74
long-chain-enoyl-CoA hydratase
|
–
–
|
| |
BRENDA:
BR451
KEGG:
R04738
MetaCyc:
LONG-CHAIN-ENOYL-COA-HYDRATASE-RXN;
RXN-14272
SABIO-RK:
4394
|
|
|
|
(11Z)-hexadec-11-enoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> (2E,11Z)-hexadec-2,11-dienoyl-CoA + reduced_flavodoxin
|
1.3.8.9
very-long-chain acyl-CoA dehydrogenase
|
–
|
| |
MetaCyc:
RXN-16557
|
|
|
|
(9Z)-tetradecenoyl-CoA + NADPH + H+ <=> (Z)-9-tetradecen-1-ol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-16553
|
|
|
|
(9Z,11E)-tetradec-9,11-dienoyl-CoA + NADPH + H+ <=> (Z9,E11)-tetradec-9,11-en-1-ol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-16550
|
|
|
|
(3S,11Z)-3-hydroxyhexadec-11-enoyl-CoA + NAD+ <=> (11Z)-3-oxohexadecenoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
|
–
|
| |
MetaCyc:
RXN-16559
|
|
|
|
(3S)-hydroxyhexadecanoyl-CoA + NAD+ <=> 3-ketohexadecanoyl-CoA + NADH + H+
|
1.1.1.211
long-chain-3-hydroxyacyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
| |
BRENDA:
BR50824
KEGG:
R04737
MetaCyc:
1.1.1.211-RXN;
RXN-14271
SABIO-RK:
4393
|
|
|
|
(Z9,E11)-tetradec-9,11-en-1-ol + acetyl-CoA <=> (Z9,E11)-tetradec-9,11-enyl_acetate + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-16549
|
|
|
|
(E)-11-tetradecenoyl-CoA + ferricytochrome_b5 + O2 + H+ <=> (9Z,11E)-tetradec-9,11-dienoyl-CoA + ferricytochrome_b5 + H2O
|
1.14.19
|
–
|
| |
MetaCyc:
RXN-16547
|
|
|
|
myristoyl-CoA + ferricytochrome_b5 + O2 + H+ <=> (E)-11-tetradecenoyl-CoA + ferricytochrome_b5 + H2O
|
1.14.19.24
acyl-CoA 11-(E)-desaturase
|
–
|
| |
MetaCyc:
1.14.99.31-RXN
|
|
|
|
(E)-11-tetradecenoyl-CoA + NADPH + H+ <=> (11E)-tetradecenol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-16555
|
|
|
|
Tetradecanol + acetyl-CoA <=> tetradecyl_acetate + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-16563
|
|
|
|
(3S,11Z)-3-hydroxyhexadec-11-enoyl-CoA <=> (2E,11Z)-hexadec-2,11-dienoyl-CoA + H2O
|
4.2.1.17
enoyl-CoA hydratase
|
–
|
| |
MetaCyc:
RXN-16558
|
|
|
|
acetyl-CoA + myristoyl-CoA <=> CoA + 3-ketohexadecanoyl-CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
| |
BRENDA:
BR29472
KEGG:
R03991
MetaCyc:
2.3.1.155-RXN;
RXN-16560
SABIO-RK:
3726
|
|
|
|
(Z)-11-tetradecen-1-ol + acetyl-CoA <=> (Z)-11-tetradecenyl_acetate + CoA
|
2.3.1
2.3.1.84
alcohol O-acetyltransferase
|
–
–
|
| |
BRENDA:
BS435202
MetaCyc:
RXN-16552
|
|
|
|
(11E)-tetradecenol + acetyl-CoA <=> (11E)-tetradecen-1-yl_acetate + CoA
|
2.3.1
|
–
|
| |
MetaCyc:
RXN-16556
|
|
|
|
(Z)-11-tetradecenoyl-CoA + NADPH + H+ <=> (Z)-11-tetradecen-1-ol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
MetaCyc:
RXN-16551
|
|
|
|
palmitoyl-CoA + ferricytochrome_b5 + O2 + H+ <=> (11Z)-hexadec-11-enoyl-CoA + ferricytochrome_b5 + H2O
|
1.14.19.5
acyl-CoA 11-(Z)-desaturase
|
–
|
| |
MetaCyc:
RXN-15112
|
|
|
|
myristoyl-CoA + NADPH + H+ <=> Tetradecanol + CoA + NADP+
|
1.2.1.84
alcohol-forming fatty acyl-CoA reductase
|
–
|
| |
BRENDA:
BS441653
MetaCyc:
RXN-16562
|
|
|
|
myristoyl-CoA + ferricytochrome_b5 + O2 + H+ <=> (Z)-11-tetradecenoyl-CoA + ferricytochrome_b5 + H2O
|
1.14.19.5
acyl-CoA 11-(Z)-desaturase
|
–
|
| |
MetaCyc:
1.14.99.32-RXN
|
|
|
|
(Z)-9-tetradecen-1-ol + acetyl-CoA <=> (Z)-9-tetradecenyl_acetate + CoA
|
2.3.1
2.3.1.84
alcohol O-acetyltransferase
|
–
–
|
| |
BRENDA:
BS435205
MetaCyc:
RXN-16554
|
|
|
|
acetyl-CoA + (9Z)-tetradecenoyl-CoA <=> CoA + (11Z)-3-oxohexadecenoyl-CoA
|
2.3.1.155
acetyl-CoA C-myristoyltransferase
|
–
|
| |
MetaCyc:
RXN-16561
|
|
|
|
palmitoyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> trans-2-hexadecenoyl-CoA + reduced_flavodoxin
|
1.3.8.9
very-long-chain acyl-CoA dehydrogenase
|
–
|
| |
MetaCyc:
RXN-16540
|
|
